Lanthanide complexes of azidophenacyl-DO3A as new synthons for click chemistry and the synthesis of heterometallic lanthanide arrays.

Synthesis and Characterization of Some Lanthanide(III) Chloro Complexes Derived from 4[N-(4’-Hydroxy-3’-Methoxybenzalidene) Amino] Antipyrine Semicarbazone and 4[N-(3’,4’,5’-Trimethoxybenzalidene) Amino]Antipyrine Semicarbazone

Lanthanide(III) chloro complexes of 4[N-(4’-hydroxy-3’-methoxybenzalidene) amino] antipyrine semicarbazone (HMBAAPS) (I) and 4[N-(3’,4’,5’-trimethoxybenzalidene) amino] antipyrine semicarbazone (TMBAAPS) (II) with the general composition LnCl3.2L (Ln = La, Pr, Nd, Sm, Gd, Tb, Dy or Ho; L = HMBAAPS or TMBAAPS) are reported. All the complexes were synthesized in ethanolic medium and refluxed the ...

Synthesis, characterization and optimization of Silica nanostructures by use of structure modifiers and ultrasonication

In recent years, using Sol-gel procedure for the purpose of laboratory and industrial synthesis of Nano-structures, and especially silica Nano-particles, has been significantly increased. In this research, silica particles were synthesized by Sol-gel procedure and their physical and chemical properties were studied by means of scanning electron microscopy (SEM), transmission electron microscopy...

Synthesis, characterization and optimization of Silica nanostructures by use of structure modifiers and ultrasonication

In recent years, using Sol-gel procedure for the purpose of laboratory and industrial synthesis of Nano-structures, and especially silica Nano-particles, has been significantly increased. In this research, silica particles were synthesized by Sol-gel procedure and their physical and chemical properties were studied by means of scanning electron microscopy (SEM), transmission electron microscopy...

White-light emission from discrete heterometallic lanthanide-directed self-assembled complexes in solution† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc00739f Click here for additional data file.

Synthesis of luminescent homo-dinuclear cationic lanthanide cyclen complexes bearing amide pendant arms through the use of copper catalysed (1,3-Huisgen, CuAAC) click chemistry.

The design and synthesis of dinuclear-lanthanide complexes possessing triazole-based bridges, formed by using copper catalysed 1,3-cycloaddition reactions between heptadentate alkyne functionalised cyclen europium or terbium complexes and di-azides (CuAAC reactions), are described. While this click reaction worked well for the formation of the homo-Eu(III) and Tb(III) bis-tri-arm cyclen N,N-dim...